Petrochemical Plants. Petchem News & Global Market Outlook: June 2007
 
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All you need to know about latest petrochemical plants, processes and market information on petrochemical industry

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Petrochemical industry plays a major role in our daily life. Almost everything that we are dependent nowadays are made from petrochemicals be it plastics, clothes, home appliances etc. Being a professional chemical engineer, one needs to keep up-to-date with fast changing petrochemical industry especially when new processes for new products, new chemicals are invented everyday.

Saturday, June 30, 2007

Petrochemical News 01.01.07

BASF Started up New Alkylethanolamines (AEOA) Plant in Geismar, Louisiana One Month Ahead of Schedule

The new plant will produce over 20 specialty amines, on top of the existing amine production facilities at the Louisiana. The Geismar plant will increase BASF’s worldwide production capacity for AEOA (alkylethanolamines) by 40 percent which is backward integrated with its existing ethylene oxide production at the site. BASF also operates AEOA plants at its Verbund site in Ludwigshafen, Germany.

KAY Chemical Expanding Chemical Plant

Kay Chemical, an Ecolab company, is expanding it's product development catalogue by investing multi million dollars for expansion of their manufacturing building on Capital Drive. Kay Chemical who runs Research & Development, Microbiology and Engineering laboratories for the evaluation and testing of new products is a leading supplier of cleaning and sanitizing products used in the fast-food and grocery markets is planning to hire additional 25 employees and new machinery and equipment over the next year.

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Saturday, June 23, 2007

Propane

Applications

  1. Propane can be used as fuel in cooking on many barbecues, portable stoves, and in motor vehicles.

  2. Domestic and industrial fuel - Propane is the fastest growing fuel source in the Third World, especially in China and India replacing the traditional woods and coals. Propane is usually shipped as LPG, a blend of propane and butane. The warmer the country, the higher the butane content, commonly 50/50 and sometimes reaching 75% butane.

  3. Refrigeration - Propane is also instrumental in providing off-the-grid refrigeration, also called gas absorption refrigerators. Made popular by the Servel company, propane-powered refrigerators are highly efficient, do not require electricity, and have no moving parts. Refrigerators built in the 1930s are still in regular use, with little or no maintenance. However, certain Servel refrigerators are subject to a recall for CO poisoning.

  4. Vehicle fuel - The advantage of propane is its liquid state at room temperature and moderate pressure. This allows fast refill times, affordable fuel tank construction, and ranges comparable to (though still less than) gasoline. Meanwhile it is noticeably cleaner (both in handling, and in combustion), results in less engine wear (due to carbon deposits) without diluting engine oil (often extending oil-change intervals), and until recently was a relative bargain in North America.

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Chemical Information and Process Technology

Propane is one of the feedstock for petrochemical industry, found mainly from the petroleum products either during refining or gas processing. Propane is not produced for its own sake, but as a byproduct of two other processes: natural gas processing and petroleum refining. The processing of natural gas involves removal of butane, propane, and large amounts of ethane from the raw gas, to prevent condensation of these volatiles in natural gas pipelines.

Additionally, oil refineries produce some propane as a by-product of production of cracking petroleum into gasoline or heating oil. The supply of propane cannot be easily adjusted to account for increased demand because of the by-product nature of propane production. About 85% of U.S. propane is domestically produced. The United States imports about 10-15% of the propane consumed each year. Propane is imported into the United States via pipeline and rail from Canada, and by tankers from Algeria, Saudi Arabia, Venezuela, Norway and the United Kingdom. After it is produced, North American propane is stored in huge salt caverns located in Fort Saskatchewan, Alberta, Canada, Mont Belvieu, Texas, and Conway, Kansas. These salt caverns were hollowed out in the 1940s and can store up to 80 million barrels of propane, if not more. When the propane is needed, most of it is shipped by pipelines to other areas of the Midwest, the North, and the South, for use by customers. Propane is also shipped by barge and rail car to selected U.S. areas.

Petrochemical industry relies heavily on gas as the feedstock. Propane together with butane are blended to produce LPG for the petrochemical industry. Some petrochemical crackers use LPG as the feedstock for further cracking into ethylene, propylene and C4 streams or known as butylenes.

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PROPANE MSDS (Material Safety Datasheet)

GENERAL

Synonyms: liquefied propane, propane gas
Molecular formula: C3H8
CAS No: 74-98-6
EC No: 200-827-9

PHYSICAL DATA

Appearance: colourless odourless gas (for precautions, small amount of unpleasant-smelling gas such as a thiol may be added to provide warning in the event of a leak.)
Melting point: -188 C
Boiling point: -44.5 C
Critical temperature: 96.67 C
Critical pressure: 41.94 atm
Vapour density: 1.55
Vapour pressure:
Specific gravity:
Flash point: -104 C (open cup)
Explosion limits: 2.4% - 9.5 %
Autoignition temperature: 468 C

STABILITY

Stable. Incompatible with strong oxidizing agents. Highly flammable. May form explosive mixtures with air.

TRANSPORTATION

UN hazard code is 2.1 which is flammable gas.

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Petrochemical News 23.06.07

Hanwha's talks with Saudi Aarbia for US$6.5 bln plant delayed

Hanwha Chemical Corp., in the process of negotiating a US$6.5 bln petrochemical project in Saudi Arabia, is facing some delays. The petrochemical plant, which will produce ethylene and propylene by cracking naphtha produced with Saudi crude. Hanwha will buy raw materials at local prices in Saudi, boosting sales. Hanwha's, Kim Seung-youn - chairman and owner is on trial for assault and kidnapping. The final deal on total amount of investment and stake sharing, due for finalization by the end of this month or early next month, along with commencement of construction, has been delayed due to the current situation.

Chem plant's license fate in balance next month

A public hearing on July 17 to consider whether the license of ink manufacturer CAI Inc. and paint maker Arnel Co. should be revoked because of "failure to follow safety procedures and/or because of the inherent inordinate risk involved with such activities at that location."

Union Carbide plant recognized for safety performance

The U.S. Department of Labor's Occupational Safety and Health Administration (OSHA) on June 22 welcomed Union Carbide Corporation’s Seadrift Operations into the prestigious Voluntary Protection Programs (VPP) at the highest, or "Star," level during a ceremony held at the company facility in Seadrift, Texas.

Plant Shut After Polluting China River

An industrial plant in eastern China has been shut after saying it accidentally discharged a toxic chemical into a river that sickened 61 villagers, state media reported Friday.

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Wednesday, June 20, 2007

Petrochemical Plant News 20.06.07

BASF: New Chinese MDI plant may be at Chongqing

BASF (Ludwigshafen) may open up an MDI plant at the Chonqing (Changshou) Chemical Industrial Park at Chongqing in western China. BASF signed memorondum of cooperation on 12 June 2007 with Chongqing Chemical and Pharmaceutical Holding (Chongquing / China) and local authorities. Expected capacity is 400,000 t/y of crude MDI. Construction beginning 2010. Chongqing Chemical may have an as yet unspecified role in the project.

ExxonMobil Chemical plans to build Florida manufacturing plant

ExxonMobil Chemical plans to build a new facility at Pensacola, Fla., to manufacture specialty elastomers and nylon as early as 2008. Exxon's proprietary Exxpro will be produced, an elastomer designed to improve the quality of automobile tire inner liners improving tire performance and durability by reducing air permeability. ExxonMobil Chemical expects to commercialize the technology in late 2007.

Mitsubishi, Kirin Brewery to build ethanol plant

Mitsubishi Corp, Japan's biggest trading firm, and Kirin Brewery Co Ltd, the No. 2 brewer, will join in a government backed “green” fuel project by building an ethanol plant on the northern island of Hokkaido. Market is for domestic. A consortium formed by the two companies and unlisted Osaka-based Japan Chemical Engineering & Machinery Co Ltd won a plant order for the project of some six billion yen (US$48.5mil). Construction starts in October and expected to produce 15,000 kilolitres of ethanol per year. Feedstocks would be excess sugar beet and low-quality wheat.

Hanwha Chemical Corp to construct USD 6.5 billion plant in Saudi Arabia

Hanwha Chemical Group of South Korea was reported to have had initiated talks with Saudi Arabia for the construction of a 6 trillion to 7 trillion won (USD 6.47 billion) petrochemical plant in Saudi Arabia.

HaiKe Chemical says China petrochem plant on course for December start-up

China's HaiKe Chemical Group Ltd reported construction of the heavy oil catalytic cracking facility is progressing as planned and operations to dtart in December. It spent 14 mil USD to build the facility using the 17 mil USD it raised from a share listing on the Alternative Investment Market in February. 3 mil USD was used for the expansion of the group's isopropyl alcohol production facilities.

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Tuesday, June 19, 2007

POM (Poly oxy methylene)

Applications

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Chemical Information and Process Technology

Mass Balance on POM (Polyoxymethylene)

3 Formaldehyde à Trioxane

Trioxane + 3 Ethylene Glycol à 3 Dioxolane + 3 Water

Polymerization of Trioxane + Dioxolane à 6 POM Copolymer

To produce 1 ton (1000kg) of POM, using the above equation; raw materials needed are as shown in Table 1:

Table 1: Raw materials for production of POM

Raw materials

Amount (kg)

Formaldehyde

2000

Ethylene Glycol

1000

Additional raw materials needed are boron trifluoride etherate and water.

Calculation

? The total equation for POM is as follows:

12 Formaldehyde + 3 Ethylene Glycol à 6 POM Copolymer

? And the chemical formulas for each are:

12 H2CO + 3 C2H6O2 à 6 [OCH2]

2 H2CO + 0.5 C2H6O2 à 1 [OCH2]

? The equation is already balanced and for each 1 mol of POM,

Ø 2 mols of Formaldehyde is needed

Ø 0.5 mols of Ethylene Glycol is needed

? Using the periodic table, the mass for each chemical can be obtained through back-calculation using their respective molecular weight. This is governed by the equation, mol = mass/molecular weight

The molecular mass for each is as follows:

? H2CO = (2 + 12 + 16)* 2 = 60

? C2H6O2 = (24 + 6 + 32) * 0.5 = 31

? OCH2 = (16 + 12 + 2)* 1 = 30

Using this calculation, the production for 1 ton of POM can be obtained by dividing each chemical by 30 and times each by 1000 kg

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Market Information

Table below shows the major POM producers:

Company

POM Tradename

Type of POM

DuPont

Delrin

Copolymer

Korean Engineering Plastics

Kepital

Homopolymer

Ticona Engineering Polymers

Celcon, Hostaform

Homopolymer

BASF

Ultraform

Homopolymer

Market Review

China domestic POM (Polyoxymethylene) market has been recovered rapidly as domestic and foreign market state have shown recovery trend in 2002, and it has maintained the recovery trend in 2003 as well. China’s current production capacity is far from satisfying the POM domestic demand, which increases the import demand. Demand in 2002 turned to increase trend, especially, order from China increased by 26% compared with the last year. In 2002, domestic POM export increase was analyzed because global economy including US economy has shown rapid recovery and China's end users have increased production constantly.


In 2002, POM producers operated fully their production facilities, and they have made production goals of 2003 as 8% up compared with the last year. It is expected that the total market demand for engineering plastics in China alone will reach 180,000 tons of POM in 2005.

DuPont, Ticona, and BASF make up 90% of the French POM market. Demand increased by 8% in the United States, with a growth rate of 5% in Europe. In Asia, POM is mainly used in the electronics sector (CDs, videocassettes). In contrast, in Europe, it is largely used in the automobile industry and the electrical appliance sector.

Korea Engineering Plastics (KEP) Overview

Founded in 1987, Korea Engineering Plastics Co., Ltd (KEP) is one of the world's leading manufacturers of Polyacetal Copolymer resin, and provides customer services around the world. KEPITAL copolymer resins can be found in engineered structural components of cutting-edge products, such as, automotive, electrical, electronics and industrial machinery. KEP develops solutions for society based on KEP's inherent strength in science and technology.

KEP was founded in March 1987 as a joint venture of Tongyang Nylon Co., Ltd. (Hyosung Corp. since 1998) in Korea, Mitsubishi Gas Chemical Company Inc. and Mitsubishi Corporation.

Kepital KEP was the first Company producing Polyacetal resin in Korea. The first commercial production began in 1988 under the brand name "KEPITAL". Ever since, KEP has been one of the engines for the growth of the Korean engineering plastic industry.

KEPEL maintains 65% of Korea’s domestic market share. KEP POM production capability is at over 65,000 MT/yr, which can cover about 10% of worldwide copolymer demand since its third expansion of manufacturing facilities. KEP is now recognized worldwide for its product quality as evidenced by a number of certifications.

KEPITAL has its own distinctive features such as:

Ø excellent thermal stability at molding

Ø exhibits better flow enabling high speed production

Ø ensures low deposit on the mold surface during processing.

BASF Overview

In its five business segments, BASF posted sales of €42.7 billion in 2005. BASF strategic goal is to continue to grow profitably. Around 81,000 employees on five continents are the key to its success.

A line of acetal polyoxymethylene (POM) copolymer products under the tradename Ultraform® are available from BASF. The Ultraform acetal product range comprises versatile engineering plastics having varied properties designed for use in exacting components capable of withstanding high stresses. The Ultraform acetal grades fulfill the demands imposed on an engineering material in especially high measure. They combine high rigidity with mechanical strength and afford good elastic properties, high toughness, dimensional stability and excellent sliding friction properties.

BASF's Ultraform® offers a number of mechanical and chemical properties which are indispensable for these plastic bearing assemblies.

Ø Ultraform has high strength and creep resistance.

Ø High abrasion and fatigue resistance together with the low friction are of major importance for the maintenance-free performance of the machine.

Ø Dimensional stability not only in production but during full product life and resistance to moisture, chemicals and

Ø The ball bearings made of Ultraform need no lubricant and withstand operating temperatures between - 40° and + 80° C. They can operate at rotation speeds of more than 5000 rpm. Other typical applications are in copiers, printers, pool cleaners, rotating beacons and domestic appliances.

Ø Chemical resistance of Ultraform® acetal, particularly with respect to conventional grades of gasoline (even those containing methanol and ethanol) as well as to diesel fuels

DuPont Overview

Founded in 1802, DuPont puts science to work by creating sustainable solutions essential to a better, safer, healthier life for people everywhere. Operating in more than 70 countries, DuPont offers a wide range of innovative products and services for markets including agriculture, nutrition, electronics, communications, safety and protection, home and construction, transportation and apparel.

After four years of development DuPont patented Delrin® in 1956 and began construction of a 20-million pound annual-capacity production plant at Parkersburg, West Virginia, completed in 1960. As manufacture commenced, total research and development costs for the project topped $50 million dollars. DuPont fully expected to recover these costs by marketing Delrin® as a general substitute for nonferrous metals, but a patent dispute and stiff competition held profitability down. As a result, DuPont focused subsequent research efforts on more sophisticated and specialized engineering polymers.

Delrin® acetal resin emerged from DuPont's efforts to capitalize on the success of nylon and the growing post World War II market for plastics and other synthetic materials. Efforts to develop a tough and heat resistant metal substitute began in the early 1950s, and by 1952 chemists in the Polychemicals Department had synthesized an inflexible polymer from formaldehyde that assistant research director Frank C. McGrew called "synthetic stone" and DuPont named Delrin®.

Despite its troubled beginnings, Delrin® thrived in the long run and has been steadily improved over the years. Today, Delrin® is a mainstay of DuPont's engineering polymers line and is widely acclaimed as a lightweight but durable low wear, low friction plastic for electronic office equipment, advanced conveyor technology, and automotive applications.

Ticona Overview

Ticona is a business of Celanese and was established in 1961 as a joint venture by the Celanese Corporation of America and Hoechst AG. It is a leading supplier of engineering plastics, and a world market leader for Hostaform®/Celcon® POM, GUR® PE-UHMW and Vectra® LCP. In 2005 its sales reached $887 million with main target markets in Europe, Americas and Asia/Pacific.

Ticona uses advanced polymer technology to produce high performance plastic materials that are used in a wide spectrum of applications - from children's toys to industrial gears, from tiny optical components to large automotive body parts. Ticona’s target industries include technological sectors such as automotive, electrical/electronics, communications technology, medical technology, industrial applications, machine and machine and plant construction and appliances.

Ticona's materials are world leaders in acetal polymers, liquid crystal polymers, long fiber reinforced thermoplastics, and ultrahigh molecular weight polyethylene. We also hold strong positions across our broad portfolio of other thermoplastics. Ticona's products serve designers and engineers in a number of key markets - automotive, appliance components, information technology, consumer & recreational products, industrial, medical & health, and others.

Ticona has about 1,800 employees in polymer production, compounding plants, and laboratory and design centers throughout the world. Ticona polymers are manufactured and sold in Europe and the Americas directly by Ticona and distributors and in Asia by Ticona, its agents and Polyplastics Co., Ltd.

Celcon / Hostaform POM is the world market leader of polyoxymethylene copolymers. It is characterized by excellent toughness and dimensional stability, outstanding spring and slip properties and good heat deflection temperature ratings and chemical resistance. The POM range includes grades for all processing methods and many different applications in various industries.

Affiliates:
Fortron Industries, Wilmington, North Carolina/US

Polyplastics Co. Ltd, Kuantan, Malaysia

Polyplastics Co. Ltd., Fuji City, Japan

Polyplastics Co. Ltd; Kaohsiung, Taiwan

PTM Engineering Plastics, Nantong, China

LIST of Global POM Producers

Table below shows the list of companies that produce POM worldwide:

Company Name

POM Tradename

Quadrant Engineering Plastic Products

Acetron®

Polymer Technology & Services

RTP Company

API - Kolon

Kocetal®

Aclo

Accucomp

ALBIS PLASTICS

Asahi

Lynex-T

Ashley Polymers

Ashlene®

BASF

Ultraform

Centroplast

Centrodal

Chase Plastics

CP Pryme®

Chem Polymer

Formax

Custom Resins

Duratel™

DSM Engineering Plastics

Plaslube®

DuPont

Delrin®

Ensinger

Tecaform™

Global Polymers

Korea Engineering Plastics (KEP)

Kepital®

Lati

Latan

Lati

Latilub

LG Chemicals

Lucet®

LNP

Lubriloy®

Mitsubishi

Iupital®

MRC Polymers

Talnex

Noveon

Stat-Tech™

Omnia Plastica

Owens Corning

Oxford Polymers

Polymer Resources

Polymersan

Polipom®

PolyOne

Edgetek®

Techmer Lehvoss

Plaslube®

Ticona

Celcon®

Ticona

Hostaform

Westlake Plastics

Pomalux®

Westlake Plastics

Dielux®

Zakłady Azotowe

Tarnoform

Zell-Metall

Zellamid®

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Health, Safety and Environment

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Plant Location and Capacities

60ktpa POM plant in China by Asahi Kasei and DuPont. Details.

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New Projects

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News

China built POM plant

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Monday, June 18, 2007

Mitsubishi Chemical Corporation

1.1 Overview

Company name

Mitsubishi Chemical Corporation

Head office

33-8 Shiba 5-chome, Minato-ku, Tokyo
108-0014, Japan

Incorporation

October 1, 1994 (Establishment: June 1, 1950)

Paid-in capital

14,508.6 billion yen

Line of business
(Consolidated)

Petrochemicals, Performance and functional products, Health care, and Others

Branch offices

Osaka, Nagoya, Fukuoka, and Sapporo

R&TD centers

Yokohama and Tsukuba

Major subsidiaries and offices

USA: NY and VA
Europe: Germany
Asia Pacific: PRC, Singapore, and Thailand

Employees

Mitsubishi Chemical Holdings Group:
32,995 (Consolidated)
Mitsubishi Chemical Corporation:
4,905 (Non-Consolidated)

Mitsubishi Chemical
Holdings Group companies

Domestic: 258/Overseas: 113

As a means of reducing costs for olefin, BTX (benzene, toluene and xylene) and other chemicals at the Olefin Centers at the Kashima and Mizushima Plants, a project--a petrochemical complex 'renaissance' plan is under development, which is also a government research initiative--by working to strengthen alliances with petroleum refining companies. Mitsubishi is also promoting a number of other initiatives involving alliances with natural resource producing countries, including entering the petroleum business in Saudi Arabia. Additionally, in order to further bolster competitiveness, consolidation of businesses with domestic chemical companies are in progress; in the areas of resin additives (plasticizers) and commodity polymers (polyolefin, vinyl chloride, polystyrene, ABS, etc.), where streamlining has become a necessity.

An advantage of the Mitsubishi Chemical Group is its comprehensive strength, which is derived from its product chains that cover from raw materials to second and third derivatives and processed products. For such products as glacial acrylic acid, 1,4-butanediol, oxo products, phenol, acrylamide and purified terephthalic acid, Mitsubishi has constructed robust product chains covering from monomers to polymer manufacturing, compounding and processed resin products, and are further diversifying and adding even greater functionality at each process stage.

The petrochemicals businesses of the Mitsubishi Chemical Group are broadly divided into basic chemicals and a large number of second and third derivative products. In the area of basic chemicals, Mitsubishi is developing an array of product chains covering a variety of solvents and resin products. These activities are led by our Olefin Centers.

1.2.1 Purified Terephthalic Acid (PTA)

Purified terephthalic acid (PTA) is the main raw material for polyester fiber, PET resins, PET films and other products. Mitsubishi Gas Chemical Company, Inc. consolidated the PTA sales business with the establishment of Dia Terephthalic Acid Corporation. Mitsubishi is also leveraging proprietary production technologies domestically at the Matsuyama Plant and overseas at production bases in South Korea, Indonesia and India. Further, with the promotion of the Daxie Island project in China, which is targeting production in September 2006, Mitsubishi is continuing to develop globally in order to meet worldwide demand.

1.2.2 C4 Chemicals

The Group is developing a wide range of C4 chemicals including 1,4-butanediol (1,4-BG), tetrahydrofuran (THF), and maleic anhydride. The 1,4-BG/THF co-production process in particular has been well received by customers and its technology is being exported overseas. The Group's derivative products span a wide range and include polytetramethylene ether glycol (PTMG), -butyrolactone (GBL), and n-methyl-2-pyrrolidone (NMP).

1.2.3 PET resins

PET resins are used in a wide variety of food container and packaging film applications, including in PET bottles, which have become a staple product of daily life. Continued growth in the global market is expected. Mitsubishi has the expertise in the product chain from PTA manufacturing to application-specific PET resin production and film molding, and establishing market competitiveness.

1.2.4 Glacial acrylic acid and derivatives

Mitsubishi manufactures glacial acrylic acid and acrylic acid ester with proprietary manufacturing technologies and catalysts. Super absorbent polymers used in disposable diapers and other products are the main application for glacial acrylic acid, while acrylic acid ester is used as a raw material in products such as paint and adhesive materials. As these products have an affinity with water, they have drawn attention as environmentally friendly materials. In addition, Sasol Dia Acrylates (Pty) Ltd., a joint venture with South Africa's Sasol Chemical Industries Ltd, commenced commercial production and sales in April 2004 of acrylic acid and its derivatives.

1.2.5 Engineering Plastics

Mitsubishi engineering plastics are superior in transparency, heat-resistance, impact-resistance and other characteristics. Mitsubishi produces polycarbonates--for which applications are expanding in a wide range of fields including automobiles, electricity and electronics--and a variety of other engineering plastics such as nylon resins and polybutylene terephthalate (PBT).

1.2.6 Performance Polymers

Based on its polymerization, modification and compounding technologies, the Group is developing and manufacturing thermoplastic elastomers, crosslinked polymers, adhesive polymers and conductive polymers with functions that include flexibility, endurance, heat resistance and adhesiveness. Mitsubishi has a product lineup that meets a broad range of diverse needs in fields that include automobiles, food products, electric machinery and medicine.

Product

Business Corporation

Production Site

Capacity

Kt/yr

Ethylene

Mitsubishi Chemical
Corporation

Mizushima
Kashima

450
828

Total

1,278

Ethylene oxide
(EO)

Mitsubishi Chemical
Corporation

Kashima

290

Total

290

Acrylic acid
(AA)

Mitsubishi Chemical
Corporation

Yokkaichi
South Africa
(Sasol Dia Acrylates (Pty)
Limited)

110
80

Total

190

Acrylic acid ester
(AE)

Mitsubishi Chemical
Corporation

Yokkaichi
South Africa
(Sasol Dia Acrylates (Pty)
Limited)

116
115

Total

231

Bisphenol-A
(BPA)

Mitsubishi Chemical
Corporation

Kurosaki
Kashima

120
100

Total

220

Styrene monomer
(SM)

Mitsubishi Chemical
Corporation

Kashima
Singapore
(Yuka Seraya Private Limited)*1

390
380

Total

770

Terephthalic acid
(TPA)

Mitsubishi Chemical
Corporation

Matsuyama
South Korea
(Sam Nam Petrochemical Co.,
Ltd.)*2
Indonesia
(PT. Mitsubishi Chemical
Indonesia)
India
(MCC PTA India Corp.
Private Lminited)

250
1,600


650


470

Total

2,970

Ethylene glycol
(EG)

Mitsubishi Chemical
Corporation

Kashima

300

Total

300

Acrylnitrile
(AN)

Dia-Nitrix Co., Ltd.

Mizushima
Otake

115
90

Total

205

PET resin for bottle

Japan Unipet
Co., Ltd.

Iwakuni
Yokkaichi
Echizen
(Echizen Polymer Co., Ltd.)

66
46
28

Total

140

Polystyrene
(PS)

PS Japan
Corporation

Yokkaichi
Chiba
Mizushima

85
252
108

Total

445

Polyvinyl chloride
(PVC)

V-Tech Corporation

Yokkaichi
Mizushima
Kawasaki

104
115
115

Total

334

Polyethylene
(HDPE)

Japan Polyprolylene
Corporation

Mizushima
Kawasaki
Oita

99
177
199

Total

475

Polyethylene
(LDPE)

Japan Polyprolylene
Corporation

Kashima
Mizushima
Kawasaki
Oita

62
65
95
123

Total

345

Polyethylene
(L-LDPE)

Japan Polyprolylene
Corporation

Mizushima
Kashima
Kawasaki

53
260
50

Total

363

Total of polyethylene

1,183

Polypropylene
(PP)

Japan Polyprolylene
Corporation

Kashima
Goi
Kawasaki
Mizushima
Yokkaichi

346
329
227
100
80

Total

1,082

1,4-butanediol
(1,4-BG)

Mitsubishi Chemical
Corporation

Yokkaichi
South Korea
(BASF Company Ltd.)*1
Taiwan
(Nan Ya Plastics Corporation)*1

100
10

15

Total

125

Polytetramethylene
Ether Glycol
(PTMG)

Mitsubishi Chemical
Corporation

Yokkaichi

35

Total

35

Polycarbonate
(PC)

Mitsubishi Chemical
Corporation

Kurosaki
South Korea
(Sam Yang Kasei Co., Ltd.)*3

40
85

Total

125

Polybutylene
terephtalate
(PBT)

Mitsubishi Chemical
Corporation

Yokkaichi

70

Total

70

*1

Off-take right

*2

Joint venture of Mitsubishi Chemical Corporation and Sam Yang Kasei Co., Ltd.
Mitsubishi Chemical Corporation's shareholding ratio is 40%.

*3

Total production capacity
Off-take right of Mitsubishi Chemical Corporation is not disclosed.

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Sunday, June 17, 2007

Lanxess Company Profile

Lanxess Company Profile

Headquarters

Germany

Employee

18,000 at 50 sites

Divisions

  • Performance Rubber,
  • Engineering Plastics,
  • Chemical Intermediates
  • Performance Chemicals

History

Separation from the Bayer Group was accomplished on 28 January 2005

Financial (in Euro mil)

  • Net Sales = 7150
  • Operating result (loss) (EBIT) = 28
  • Earnings before interest, taxes, depreciation, & amortisation (EBITDA) = 341
  • Earnings (loss) per share (Euro) = 0.75

Divesture of its textiles processing chemicals business

In November 2006, Egeria agreed to buy Lanxess' textiles processing chemicals business for Euro54m ($69m). The divestiture is expected to be completed by year-end 2006.

Saltigo

Saltigo was created out of Lanxess's fine chemicals business unit, which achieved sales of $500m in 2005 and has around 1,400 employees. As a wholly-owned subsidiary of Lanxess, Saltigo provides services to the pharmaceutical, agrochemical and specialty chemicals industries.

Portfolio

Performance Rubber (in 2005 it had sales of Euro1.6m and around 3,000 employees)

Butyl Rubber: Butyl is the only rubber to be impermeable to air. The product family comprises three main types: butyl; bromobutyl; and chlorobutyl.

Polybutadiene Rubber: Polybutadiene rubber and solution styrene-butadiene rubber.

Technical Rubber Products: Polychloroprene solid rubber and latices (CR); ethylene-propylene rubber (EP D M); nitrile rubber (NBR); hydrogenated nitrile rubber (HNBR); ethylene-vinylacetate rubber (EVM); and styrene-butadiene rubber (SBR).

  • PBR plants in:

Dormagen (Germany), Port Jérôme (France), Orange 250 ktpa (Texas)

  • Butyl Rubber plants in:

Zwijndrecht 115 ktpa (Belgium), Sarnia 90 ktpa (Canada)

Chemical Intermediates (in 2005 it had sales of Euro1.5m and around 3,300 employees)

Basic Chemicals: Supplier of industrial chemicals with a strong position in aromatic compounds.

Fine Chemicals: Development and production of fine chemicals, agrochemical intermediates, pharmaceutical intermediates, and corresponding supply of services.

Inorganic Pigments: Colouring of building materials such as roofing tiles and pavers, surface coatings, plastics and paper, plus special applications in the fields of toner pigments, arsenic adsorbers and catalysts.

Engineering Plastics (in 2005 it had sales of Euro1.7m and around 3,400 employees)

Lanxess claims to be a major supplier of polymers through its engineering plastics segment.

Dorlastan Fibres & Monofil: Synthetic elastic fibres for fashion wear, occupational clothing, sportswear bandages and diapers. Polyamide and copolyamide wires for industrial fabrics for the paper industry, fishing, ships' ropes and hawsers, and agriculture. As of November 2005, Lanxess has finalised a deal to sell its Dorlastan fibres business to Japan's Asahi Kasei Fibres for an undisclosed amount.

Semi-Crystalline Products: Plastics are suitable for applications in the automotive and electrical/electronics industries (Durethan, polyamide 6 and 6.6, Pocan polybutylene terephthalate; glass fibres for the reinforcement of thermoplastics, thermosets and polyurethanes, caprolactam and adipic acid).

Styrenic Resins: Range of products include: ABS, SAN and PA-ABS plastics.

As from 1 March 2006, Lanxess finalised a deal to sell its Dorlastan fibres business to Japan's Asahi Kasei Fibres for an undisclosed amount. The deal was previously announced in November 2005.

Performance Chemicals (in 2005 it had sales of Euro1.9m and around 4,700 employees)

Functional Chemicals: Plastics additives (plasticisers, blowing agents, bonding agents, modifiers and emulsifiers); phosphorus and speciality chemicals (flame retardants, water chemicals, synthesis chemicals, reducing agents, complexing and dispersing agents).

Ion Exchange Resins: Lewatit ion exchange resins for water treatment, the food industry, catalysis and chemical processes, and the pharmaceutical industry.

Leather: Supplier of leather chemicals and system solutions with a broad product portfolio for all stages of leather manufacture including inorganic and synthetic tanning materials, preservatives and fat-liquoring agents, dyes, and tanning and finishing agents.

Material Protection Products: Range of biocides and speciality active ingredients for wood preservatives/antifouling products, disinfectants/personal care products, beverage preservatives and industrial preservatives (paints, mineral slurries, dry film and in-can preservation, corrosion inhibitors, etc.).

Paper: Range of fluorescent brightening agents, colourants, retention aids, and wet/dry strength agents, as further process and functional chemicals and other specialty products.

Rhein Chemie: Additives for the rubber, lubricants, polyurethanes and plastics industries.

Rubber Chemicals: Supplier of rubber chemicals for the tyre industry and for the manufacture of technical rubber products (Vulkanox antioxidants, Vulkacit accelerators and specialty chemicals).

Textile Processing Chemicals: For pre-treatment, dyeing auxiliaries, finishing and textile printing.

On 3 April 2006, Kemira confirmed that it had completed the acquisition of Lanxess's paper chemicals business. The responsible antitrust authorities agreed to the transaction on 1 March 2006 and Kemira took over the business on 1 April 2006. The deal was previously announced on 20 December 2005.

Labels:

Formaldehyde

Applications

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Mass Balance on Formaldehyde

2 Methanol + Oxygen à 2 Formaldehyde + 2 Water

To produce 1 tonne (1000kg) of Formaldehyde, using the above equation; raw materials needed are as shown in Table 1:

Table 1: Raw materials for production of Formaldehdye

Raw materials

Amount (kg)

Methanol

1067

Oxygen

533

Calculation

? The total equation for Formaldehyde is as follows:

1 mol Methanol + 0.5 mol Oxygen à 1 mol Formaldehyde + 1 mol Water

? And the chemical formulas for each are:

CH3OH + 0.5 O2 à H2CO + H2O

? For each 1 mol of Formaldehyde,

Ø 1 mol of Methanol is needed

Ø 0.5 mols of Oxygen is needed

? Using the periodic table, the mass for each chemical can be obtained through back-calculation using their respective molecular weight. This is governed by the equation, mol = mass/molecular weight

The molecular mass for each is as follows:

? CH3OH = (12 + 3 + 16 + 1)* 1 = 32

? O2 = (32) * 0.5 = 16

? H2CO = (16 + 12 + 2)* 1 = 30

? H2O = (2 + 16)* 1 = 18

Using this calculation, the production for 1 tonne of Formaldehyde can be obtained by dividing each chemical by 30 and times each by 1000 kg

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Saturday, June 9, 2007

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